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   rec.arts.sf.science      Real and speculative aspects of SF scien      45,986 messages   

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   Message 45,710 of 45,986   
   Joel Polowin to Thomas Koenig   
   Re: Dragonbreath   
   16 Sep 20 21:02:55   
   
   XPost: rec.arts.sf.written   
   From: jpolowin@sympatico.ca   
      
   On 2020-09-16 1:57 PM, Thomas Koenig wrote:   
   > (Actually, it's very probably wild UV-induced chemistry.   
   > In the absence of oxygen and with UV light from the Sun,   
   > just about anything can form and be fairly stable).   
      
   I don't think phosphines are likely to be very stable to UV photolysis,   
   even in a reducing environment.  Their concentration would come from the   
   equilibrium between their weird-ass synthesis and their being   
   decomposed.   
      
   But my intuition is biased from my having worked with several phosphine   
   compounds in an oxygen atmosphere.  Where they were more or less   
   spectacularly unstable.   
      
   Joel   
      
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