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|    sci.optics    |    Discussion relating to the science of op    |    12,750 messages    |
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|    Message 11,195 of 12,750    |
|    Timothy Sutter to All    |
|    Re: Analogy between chromophore and auxo    |
|    01 Oct 12 00:11:45    |
      XPost: sci.chem       From: a202010@lycos.com-              > > Timothy Sutter wrote:              > > > Salmon Egg wrote:              > > > > Can a dopant be considered to be an auxochrome?              > > > if you were to say that a 'sensitizer' heightens       > > > the luminosity of the 'activator,' then you could       > > > say it was 'like' an auxochrome which may heighten       > > > the intensity of the chromophore's color,              > > > is it -possible- to make a useful analogy?              > > > maybe sort of...              > > it's sort of like, you'd be saying the -cloth-       > > was the host lattice for the dye              > > in the same way as CaF2 is the host lattice       > > for Eu3+ ions.              > > but in this respect, Eu3+ would -be- the 'dye'                     oh, sorry, i meant eu2+                     > > but then you'd be saying that it was something       > > about the CaF2 lattice that set up an energetic       > > situation in the europium that resulted       > > in the fluorescence,              > at least insamuch as different lattices       > may result in different spectra.              > > whereas, you wouldn't say that there was anything       > > about the -cloth- that comntributed to the color       > > of the dye, at all.       >       > > so, any analogy would probably be centered around       > > the case of a sensitizer/activator where the sensitizer       > > could be said to be behaving somewhat like an auxochrome       > > in the overall crystal system.       >       > > if you just have an activator and no sensitizer,       > > there doesn't seem to be any real similarity at all.              --- SoupGate-Win32 v1.05        * Origin: you cannot sedate... all the things you hate (1:229/2)    |
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