Forums before death by AOL, social media and spammers... "We can't have nice things"
|    sci.optics    |    Discussion relating to the science of op    |    12,750 messages    |
[   << oldest   |   < older   |   list   |   newer >   |   newest >>   ]
|    Message 11,837 of 12,750    |
|    Phil Hobbs to haiticare2011@gmail.com    |
|    Re: How to violate the (Clausius stateme    |
|    26 Apr 14 12:08:06    |
      From: hobbs@electrooptical.net              On 4/25/2014 9:38 AM, haiticare2011@gmail.com wrote:       > On Thursday, April 24, 2014 10:59:45 AM UTC-4, Phil Hobbs wrote:       >       >       >>       >> Heat flows from hot to cold because in statistical mechanics, the ratio       >>       >> of the probabilities (basically the state densities) favours that       >>       >> direction by so large a factor that it's overwhelmingly probable that no       >>       >> vaguely macroscopic hot object has ever got hotter by spontaneous heat       >>       >> transfer from a colder object in the entire history of the universe.       >>       >       >> Dr Philip C D Hobbs       >       > "Statistical mechanics" sounds complex and authoritarian, but it is just a       way       > to calculate gas laws, historically. But it gets violated every instant of       time       > - it's called Brownian Motion, and Einstein the first to examine it       > theoretically.       > To say that statistical mechanics precludes violating it is like saying,       since       > all electric currents in solid conductors cancel out, then manipulation of       > electrons is impossible.              Nonsense. What I said was that (due to the exponential increase in the       number of available states in the higher-entropy direction) the ratio of       the probabilities of heat flowing hot-to-cold vs. cold-to-hot for any       vaguely macroscopic system is so very large that it's overwhelmingly       likely that it has never happened in the lifetime of the universe.              This isn't intimidation, it's undergraduate thermodynamics. Elementary       books such as Kittel's "Thermal Physics" have it. All the math you need       is permutations and Stirling's formula for the gamma function.              > It's true, perpetual motion machines are to be treated with skepticism, but       as       > a point in the philosophy of science, there is no law that precludes them on       > theoretical grounds.              Not so, see above for an example. Natural laws are summaries of       observed behaviour, not logical axioms.              And we all have to decide what is and is not worth spending our time on.        Discussing this stuff on Usenet is strictly a recreational activity on       my end.              Cheers              Phil Hobbs                     --       Dr Philip C D Hobbs       Principal Consultant       ElectroOptical Innovations LLC       Optics, Electro-optics, Photonics, Analog Electronics              160 North State Road #203       Briarcliff Manor NY 10510              hobbs at electrooptical dot net       http://electrooptical.net              --- SoupGate-Win32 v1.05        * Origin: you cannot sedate... all the things you hate (1:229/2)    |
[   << oldest   |   < older   |   list   |   newer >   |   newest >>   ]
(c) 1994, bbs@darkrealms.ca