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|    sci.chem    |    Chemistry and related sciences    |    55,615 messages    |
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|    Message 53,658 of 55,615    |
|    Norm X to Treon Verdery    |
|    Re: battery technologies    |
|    02 Aug 15 16:33:24    |
      From: nobody@nowhere.com              On 2015-08-02 10:15 AM, Treon Verdery wrote:       > Do you think that lithium with liquid argon could be particlized to              duoatomic size from the nonreactivity of the liquid gas solvent That would              produce the higjest surface area electrochemistry thus higher amperage       >              A traditional recipe for a highly reactive dispersion of sodium calls       for rapid stirring (magnetic stir bar) in refluxing toluene. I think the       eventual product might be considered a colloidal suspension. This works       because the melting point of sodium is ~98 C. and the boiling point of       toluene is 111 C. Liquid argon is too cold. Lithium melts at 180.5 C. I       think you would have better luck making a non-settling dispersion       (colloid) of lithium by adapting the recipe for sodium and selecting a       suitable high boiling organic. I note that naphthalene has a boiling       point of ~218. This is so self-evident to me that I think it has been       done. Look for a recipe in the literature. Take note of the high melting       point of naphthalene, 78.2 C. So instead of a water condenser, one would       use an air condenser. It is always nice to use a trickle of N2 through a       capillary to promote steady boiling and to displace air. Once the       reaction is complete and the apparatus is cold, one could recover highly       reactive Li, first in a nitrogen glove box and then under high vacuum       with gentle heat to remove excess naphthalene. I think a lyophilizer       might be convenient.              --- SoupGate-Win32 v1.05        * Origin: you cannot sedate... all the things you hate (1:229/2)    |
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