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|    Message 54,519 of 55,615    |
|    barneydpitt@gmail.com to Ermanno Borra    |
|    Re: Question: How to remove oxide from g    |
|    21 Feb 19 09:11:59    |
      On Thursday, 1 October 1992 20:58:41 UTC+1, Ermanno Borra wrote:       > I wonder whether somebody can suggest solutions to my       > problem. I pour either liquid gallium or a Ga-In eutectic in a container,       > and find that the surface (several feet across) is covered with a thick       > layer of oxide scum. The problem occurs during stirring, that occurs       > just when I pour Ga After pouring, I do not stir the liquid again.       > I would like to get rid of the opaque oxide scum and get a shiny       > optical quality surface. Although it is in principle possible to work in       > an inert atmosphere and avoid the oxide, it is difficult to do so in       > practice, because of our setup. I know that, in an oxygen atmosphere,       > an oxide layer forms instantly but this is OK since the oxide layer that       > forms on an undisturbed surface is very thin and protects the Ga       > below from oxidation (like it does with Al). My real problem occurs at       > the moment of pouring since the liquid is stirred and we get too much       > thick messy oxide. Ideally, I would like to remove the oxide with       > chemical means, get a clean Ga surface that can be oxidized with the       > very thin layer of oxide that naturally forms on an undisturbed       > surface.       > I have tried to expose the oxide to HCl vapors. The surface becomes       > more reflective but its quality is not good enough for my application       > (using it as a an optical mirror).       >        > If you have a suggestion, please email at borra@phy.ulaval.ca       >       > Thanks,       > E.F. Borra              Gallium oxide + HCl -> gallium trichloride + water              Gallium trichloride is soluble in water, so it can be washed away along with       any excess HCl. You can do this with the EGaIn as a solid or a liquid, though       probably easier as a solid.              --- SoupGate-Win32 v1.05        * Origin: you cannot sedate... all the things you hate (1:229/2)    |
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